Aryl chlorides and bromides can be easily prepared by electrophilic substitution of arenes with chlorine and bromine respectively in the presence of Lewis acid catalysts. But why does preparation of aryl iodides requires presence of an oxidising agent?

 
 
  • Pankaj Singh answered April 7, 2018, 1:43 p.m. at

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Iodination reactions are reversible in nature. To carry out the reaction in the forward direction, HI formed during iodination is removed by oxidation. HIO4 is used as an oxidising agent.

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asked on Apr 07, 2018 at 13:42

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